Carbon–Phosphorus Bond Formation by Enantioselective Palladium‐Catalyzed Allylation of Diphenylphosphine Oxide | Zendy

Zhang Liang | Zendy; Liu Wei | Zendy; Zhao Xiaoming | Zendy

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Carbon–Phosphorus Bond Formation by Enantioselective Palladium‐Catalyzed Allylation of Diphenylphosphine Oxide

Author(s) -

Zhang Liang,

Liu Wei,

Zhao Xiaoming

Publication year - 2014

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201403024

Subject(s) - chemistry , diphenylphosphine oxide , allylic rearrangement , enantioselective synthesis , diphenylphosphine , phosphonate , palladium , catalysis , medicinal chemistry , organic chemistry , phosphorus , phosphine

The enantioselective Pd‐catalyzed allylation of diaryl‐substituted allylic carbonates and diphenylphosphine oxide was investigated. This method gave allylic diphenylphosphine oxides in yields up to 95 % with 97 % ee . Pd‐catalyzed allylation of ( E )‐methyl allyl carbonates with diisopropyl phosphonate was also examined.

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