A General, Regiospecific Synthetic Route to Perfluoroalkylated Arenes via Arenediazonium Salts with R F Cu(CH 3 CN) Complexes | Zendy

Jiang DongFang | Zendy; Liu Chao | Zendy; Guo Yong | Zendy; Xiao JiChang | Zendy; Chen QingYun | Zendy

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A General, Regiospecific Synthetic Route to Perfluoroalkylated Arenes via Arenediazonium Salts with R F Cu(CH 3 CN) Complexes

Author(s) -

Jiang DongFang,

Liu Chao,

Guo Yong,

Xiao JiChang,

Chen QingYun

Publication year - 2014

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201402820

Subject(s) - chemistry , ether , trapping , medicinal chemistry , organic chemistry , polymer chemistry , combinatorial chemistry , biology , ecology

A mild method of converting arylamines into perfluoroalkylated arenes is described. Relatively stable R F Cu(CH 3 CN) complexes are used as perfluoroalkylating agents, which react smoothly with arenediazonium salts to produce various perfluoroalkylarenes in good yields. Based on the results of clock trapping experiments with diallyl ether, a radical process might be involved in the reaction.

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