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Convenient Formation of Triarylphosphines by Nickel‐Catalyzed C–P Cross‐Coupling with Aryl Chlorides
Author(s) -
Sun Meng,
Zang YuShi,
Hou LeKai,
Chen XiangXiang,
Sun Wei,
Yang ShangDong
Publication year - 2014
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201402660
Subject(s) - chemistry , phosphine , aryl , nickel , catalysis , bond cleavage , combinatorial chemistry , cleavage (geology) , functional group , coupling reaction , medicinal chemistry , organic chemistry , stereochemistry , alkyl , geotechnical engineering , fracture (geology) , engineering , polymer
A convenient strategy has been developed for the preparation of various phosphine ligands in good to excellent yields through a nickel‐catalyzed C–P bond‐forming step. This reaction proceeded smoothly and tolerated a variety of functional groups to provide a new method for the synthesis of important phosphine ligands through the direct cleavage of a C–Cl bond.