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Synthesis of Substituted Biaryls through Gold‐Catalyzed Petasis–Ferrier Rearrangement of Propargyl Ethers
Author(s) -
Pati Kamalkishore,
Alabugin Igor V.
Publication year - 2014
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201402469
Subject(s) - chemistry , propargyl , catalysis , organic chemistry , combinatorial chemistry
Au‐catalyzed cycloisomerization of aryl propargyl ethers provides controlled transition from alkyne to carbonyl chemistry followed up by a Petasis–Ferrier rearrangement/aromatization cascade leading to substituted biaryls with functionalized naphthalene cores.