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Pyridyl‐Decorated Self‐Folding Heptaamide Cavitands as Ligands in the Rhodium‐Catalyzed Hydrogenation of Norbornadiene
Author(s) -
Korom Saša,
Ballester Pablo
Publication year - 2014
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201402385
Subject(s) - norbornadiene , chemistry , rhodium , cationic polymerization , catalysis , organic chemistry , folding (dsp implementation) , polymer chemistry , combinatorial chemistry , electrical engineering , engineering
The different binding geometries exhibited in solution by the Rh I cationic complexes of three regioisomeric self‐folding heptaamide cavitands, each decorated with one pyridyl group at the upper rim, are taken into account to explain the diverse distributions of products obtained when these complexes are employed as catalysts for the hydrogenation of norbornadiene.