Mono‐ vs. Dinuclear Gold‐Catalyzed Intermolecular Hydroamidation | Zendy

SerranoBecerra Juan M. | Zendy; Maier Alexander F. G. | Zendy; GonzálezGallardo Sandra | Zendy; Moos Eric | Zendy; Kaub Christoph | Zendy; Gaffga Maximilian | Zendy; NiednerSchatteburg Gereon | Zendy; Roesky Peter W. | Zendy; Breher Frank | Zendy; Paradies Jan | Zendy

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Mono‐ vs. Dinuclear Gold‐Catalyzed Intermolecular Hydroamidation

Author(s) -

SerranoBecerra Juan M.,

Maier Alexander F. G.,

GonzálezGallardo Sandra,

Moos Eric,

Kaub Christoph,

Gaffga Maximilian,

NiednerSchatteburg Gereon,

Roesky Peter W.,

Breher Frank,

Paradies Jan

Publication year - 2014

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201402068

Subject(s) - chemistry , intermolecular force , xantphos , cationic polymerization , reactivity (psychology) , catalysis , counterion , solvent , medicinal chemistry , polymer chemistry , organic chemistry , palladium , ion , molecule , medicine , alternative medicine , pathology

Mono‐ and dinuclear gold catalysts were investigated in the intermolecular hydroamidation of olefins. Upon activation of [Ph 3 PAuCl] and [xantphos(AuCl) 2 ] with various silver salts (AgOTf, Ag[BF 4 ], and Ag[SbF 6 ]), diverging reactivity of the resulting cationic gold complexes was observed. It was found that both the binding ability of the counterion and the solvent have a significant impact on the reactivity of the mono‐ and dinuclear complexes.

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