Sulfur–Carbon Bond Formation through Ring‐Opening of Triazolothiadiazole with Organometallics | Zendy

Othman Raja Ben | Zendy; Massip Stéphane | Zendy; Marchivie Mathieu | Zendy; Jarry Christian | Zendy; Vercouillie Johnny | Zendy; Chalon Sylvie | Zendy; Guillaumet Gérald | Zendy; Suzenet Franck | Zendy; Routier Sylvain | Zendy

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Sulfur–Carbon Bond Formation through Ring‐Opening of Triazolothiadiazole with Organometallics

Author(s) -

Othman Raja Ben,

Massip Stéphane,

Marchivie Mathieu,

Jarry Christian,

Vercouillie Johnny,

Chalon Sylvie,

Guillaumet Gérald,

Suzenet Franck,

Routier Sylvain

Publication year - 2014

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201400151

Subject(s) - chemistry , sulfanyl , ring (chemistry) , alkyl , sulfur , aryl , sequence (biology) , carbon fibers , organic chemistry , medicinal chemistry , stereochemistry , combinatorial chemistry , biochemistry , materials science , composite number , composite material

An efficient and convenient method was developed for the formation of S ‐substituted thiotriazoles through an unprecedented organometallic addition and subsequent ring‐opening sequence of 3‐substituted [1,2,4]triazolo[3,4‐ b ][1,3,4]thiadiazole. The method is applicable to a wide range of substrates containing different functional groups and furnishes excellent yields of the corresponding N ‐unsubstituted 3‐ or 5‐alkyl, aryl, alkynyl and alkenyl sulfanyl‐1,2,4‐triazole products.

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