Hidden Flexibility of Strychnine | Zendy

Schmidt Manuel | Zendy; Reinscheid Frauke | Zendy; Sun Han | Zendy; Abromeit Hans | Zendy; Scriba Gerhard K. E. | Zendy; Sönnichsen Frank D. | Zendy; John Michael | Zendy; Reinscheid Uwe M. | Zendy

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Hidden Flexibility of Strychnine

Author(s) -

Schmidt Manuel,

Reinscheid Frauke,

Sun Han,

Abromeit Hans,

Scriba Gerhard K. E.,

Sönnichsen Frank D.,

John Michael,

Reinscheid Uwe M.

Publication year - 2014

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201301760

Subject(s) - strychnine , chemistry , rigidity (electromagnetism) , flexibility (engineering) , computational chemistry , molecule , structural rigidity , organic chemistry , physics , quantum mechanics , biochemistry , statistics , mathematics , geometry

The prototypic molecule for conformational rigidity, that is, strychnine, exhibits fast conformational exchange on the NMR timescale at room temperature. A comprehensive description of this up‐to‐now‐hidden stereodynamic behavior is presented, which combines experimental and computational data.

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