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Copper‐Catalyzed Vinylsilane Allylation
Author(s) -
Cornelissen Loïc,
Vercruysse Sébastien,
Sanhadji Ayoub,
Riant Olivier
Publication year - 2014
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201301360
Subject(s) - vinylsilane , chemistry , copper , catalysis , halogen , organic chemistry , salt (chemistry) , cyclopentanes , combinatorial chemistry , alkyl
Soft reaction conditions, particularly important in total synthesis, have dragged many researchers into the field of silylated organic compounds. Hereby, we describe a new copper‐catalyzed vinylsilane transformation. Various vinylsilanes were allylated by using a copper(I) salt, and this led to the formation of polysubstituted 1,4‐dienes bearing sensitive moieties such as halogens, ketones, and aldehydes.