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The Anti‐Bredt Red Flag! Reassignment of Neoveratrenone
Author(s) -
Savchenko Andrei I.,
Williams Craig M.
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201301308
Subject(s) - chemistry , stereochemistry , flag (linear algebra) , algebra over a field , pure mathematics , mathematics
The bicyclo[3.3.1]non‐1‐en‐3‐one motif, which has yet to be observed in natural products, was recently reported within the skeleton of neoveratrenone. On the basis of Bredt's rule, a plausible reassignment matching closely the C‐nor‐D‐homo steroidal ring system has been proposed herein.