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t Bu 3 P‐Coordinated 2‐Phenylaniline‐Based Palladacycle Complexes as Precatalyst for Pd‐Catalyzed Coupling Reactions of Aryl Halides with Polyfluoroarenes by a C–H Activation Strategy
Author(s) -
Zhang HongHai,
Dong Jie,
Hu QiaoSheng
Publication year - 2014
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201301272
Subject(s) - chemistry , aryl , halide , catalysis , coupling reaction , coupling (piping) , palladium , medicinal chemistry , combinatorial chemistry , organic chemistry , alkyl , mechanical engineering , engineering
A t Bu 3 P‐coordinated 2‐phenylaniline‐based palladacycle complex was demonstrated to be an efficient precatalyst for Pd‐catalyzed coupling reactions of aryl halides with polyfluoroarenes that operates through a C–H activation strategy. The ready accessibility and ease of handling of the complex and the high yields of the reaction makes this palladacycle complex an attractive precatalyst for the cross‐coupling reaction of aryl halides with polyfluoroarenes.