Regioselective, Direct  meso ‐Functionalization of Sulfur‐Bridged 5,16‐Dihydro[22]annulene(2.1.2.1) | Zendy

Singh Kamaljit | Zendy; Sharma Shivali | Zendy; Sharma Amit | Zendy; Kaur Paramjit | Zendy

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Regioselective, Direct meso ‐Functionalization of Sulfur‐Bridged 5,16‐Dihydro[22]annulene(2.1.2.1)

Author(s) -

Singh Kamaljit,

Sharma Shivali,

Sharma Amit,

Kaur Paramjit

Publication year - 2014

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201301171

Subject(s) - chemistry , annulene , regioselectivity , sulfur , surface modification , aldehyde , condensation , hydrocarbon , stereochemistry , combinatorial chemistry , organic chemistry , catalysis , thermodynamics , physics

The direct incorporation of task‐specific substituents exclusively at the meso positions of neutral sulfur‐bridged 5,16‐dihydro[22]annulene(2.1.2.1) is described. This method allows for the incorporation of long hydrocarbon chains, which are otherwise not easily accessible through a conventional aldehyde condensation approach.

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