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FeCl 3 ‐Catalyzed Self‐Condensation of Enamides for the Synthesis of Enamido‐Substituted Nitrogen‐Containing Quaternary Carbon Centers
Author(s) -
Zhao MiNa,
Du Wei,
Ren ZhiHui,
Wang YaoYu,
Guan ZhengHui
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201301005
Subject(s) - chemistry , quaternary carbon , catalysis , nitrogen , condensation , carbon fibers , condensation reaction , organic chemistry , quaternary , polymer chemistry , enantioselective synthesis , physics , materials science , biology , composite number , composite material , thermodynamics , paleontology
The FeCl 3 ‐catalyzed self‐condensation of enamides offers a new strategy for the synthesis of enamido‐substituted nitrogen‐containing quaternary carbon centers, which are attractive structures in organic chemistry. The reaction affords nitrogen‐containing quaternary carbon centers in good yields under mild reaction conditions. The catalytic system was also employed in the condensation of enamides with indoles for the synthesis of bis‐indoles.