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The Chemiexcitation of the Chemiluminescence of Lophine Peroxide Anions via a Partially Cyclic Transition State
Author(s) -
Lu Gonghao,
Wada Jun,
Kimoto Takashi,
Iga Hiroshi,
Nishigawa Hideki,
Kimura Masaru,
Hu Zhizhi
Publication year - 2014
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201300976
Subject(s) - chemistry , chemiluminescence , dioxetane , peroxide , photochemistry , organic chemistry
It was shown that acyclic intermediates play a role in the chemiexcitation of the chemiluminescence (CL) of lophine peroxides in addition to the dioxetane intermediates. Because the CL efficiencies of position‐isomers ( R )‐ 9 and ( R )‐ 10 , which theoretically give the common dioxetane intermediate, were different, the different CL efficiencies are attributable to the CL mechanism involving a partially cyclic transition structure at the chemiexcitation step.