Palladium‐Catalyzed Cross‐Coupling Reaction of Functionalized Aryl‐ and Heteroarylbismuthanes with 2‐Halo(or 2‐Triflyl)azines and ‐diazines | Zendy

Petiot Pauline | Zendy; Gag Alexandre | Zendy

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Palladium‐Catalyzed Cross‐Coupling Reaction of Functionalized Aryl‐ and Heteroarylbismuthanes with 2‐Halo(or 2‐Triflyl)azines and ‐diazines

Author(s) -

Petiot Pauline,

Gag Alexandre

Publication year - 2013

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201300850

Subject(s) - chemistry , palladium , aryl , catalysis , reagent , coupling reaction , bismuth , coupling (piping) , combinatorial chemistry , halo , organic chemistry , mechanical engineering , alkyl , physics , quantum mechanics , galaxy , engineering

The palladium‐catalyzed cross‐coupling of highly functionalized organobismuthanes with 2‐halo(or 2‐triflyl)pyridines, ‐pyrimidines, ‐pyrazines, and ‐pyridazines is reported. The reaction tolerates numerous functional groups, including aldehydes. The synthesis of a shelf‐stable (formylphenyl)bismuth reagent and its use in a cross‐coupling reaction is also described.

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