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Synergistic Recognition of Halide Anions and Saccharides by Oligohydrazide Foldamers
Author(s) -
Bie Fusheng,
Wang Ying,
Shang Jie,
Gallagher Nolan M.,
Jiang Hua
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201300817
Subject(s) - chemistry , halide , oligomer , hydrazide , molecular recognition , chloride , polymer chemistry , combinatorial chemistry , organic chemistry , molecule
We synthesized and characterized a new kind of hydrazide oligomer that contains two different types of binding moieties for halide anions and saccharides. The addition of either halide anions or saccharides can induce the oligomers to adopt folded conformations. More interestingly, the oligomers are able to complex both chloride anions and saccharides in the cavity at the same time, implying a synergistic molecular recognition.