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Palladium(0)‐Catalyzed Cross‐Couplings of 2‐Bromophosphinine
Author(s) -
Kostenko Nataliya,
Ericsson Cecilia,
Engqvist Magnus,
Gonzalez Susana Villa,
Bayer Annette
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201300710
Subject(s) - negishi coupling , chemistry , palladium , catalysis , aryl , scope (computer science) , coupling (piping) , combinatorial chemistry , coupling reaction , organic chemistry , alkyl , computer science , programming language , mechanical engineering , engineering
A new Negishi‐type cross‐coupling of 2‐bromophosphinine has been developed. The new method expands the scope of palladium‐catalyzed couplings to monobromophosphinines, which have been considered as poor substrates so far. Moreover, aryl‐, alkenyl‐, and alkynylzinc bromides were found to be effective coupling partners.