Rapid Solvent‐Free Synthesis of Pyridyl‐Functionalised [5]Polynorbornane‐Based Ligands for Metal–Organic Rings and Cages | Zendy

Johnstone Mark D. | Zendy; Frank Marina | Zendy; Clever Guido H. | Zendy; Pfeffer Frederick M. | Zendy

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Rapid Solvent‐Free Synthesis of Pyridyl‐Functionalised [5]Polynorbornane‐Based Ligands for Metal–Organic Rings and Cages

Author(s) -

Johnstone Mark D.,

Frank Marina,

Clever Guido H.,

Pfeffer Frederick M.

Publication year - 2013

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201300647

Subject(s) - chemistry , cycloaddition , chelation , imide , solvent , metal , nuclear magnetic resonance spectroscopy , combinatorial chemistry , stereochemistry , polymer chemistry , organic chemistry , catalysis

A solvent‐free multicomponent protocol for the rapid (< 30 min) synthesis of pyridyl‐functionalised [5]polynorbornane ligands is described in which both 1,3‐dipolar cycloaddition and imide formation occur. The ligands produced by this approach have been incorporated into new Pd and Pt M 1 L 2 chelate complexes as well as an M 2 L 4 cage as elucidated from NMR spectroscopy, ESI‐MS and computational data.

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