Selectfluor‐Mediated Fluorination and C–C Bond Cleavage of Cyclohexene‐Fused Isoxazoline  N ‐Oxides | Zendy

R.R. Rajawinslin | Zendy; Raihan Mustafa J. | Zendy; Janreddy Donala | Zendy; Kavala Veerababurao | Zendy; Kuo ChunWei | Zendy; Kuo TingShen | Zendy; Chen MeiLing | Zendy; He ChiuHui | Zendy; Yao ChingFa | Zendy

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Selectfluor‐Mediated Fluorination and C–C Bond Cleavage of Cyclohexene‐Fused Isoxazoline N ‐Oxides

Author(s) -

R.R. Rajawinslin,

Raihan Mustafa J.,

Janreddy Donala,

Kavala Veerababurao,

Kuo ChunWei,

Kuo TingShen,

Chen MeiLing,

He ChiuHui,

Yao ChingFa

Publication year - 2013

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201300599

Subject(s) - selectfluor , chemistry , bond cleavage , cleavage (geology) , cyclohexene , organic chemistry , medicinal chemistry , catalysis , geotechnical engineering , fracture (geology) , engineering

A rapid method for the synthesis of long‐chain fluorinated compounds using a C–C bond‐cleavage reaction was developed. Selectfluor was the most effective fluorinating agent of those tested in this study. Long‐chain fluoro dioxo nitriles were formed from isoxazoline N ‐oxides via nitroso intermediates.

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