Silver‐Catalyzed Highly Regioselective Phosphonation of Arenes Bearing Electron‐Withdrawing Groups | Zendy

Mao Xuerong | Zendy; Ma Xiao | Zendy; Zhang Shuwei | Zendy; Hu Hongwen | Zendy; Zhu Chengjian | Zendy; Cheng Yixiang | Zendy

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Silver‐Catalyzed Highly Regioselective Phosphonation of Arenes Bearing Electron‐Withdrawing Groups

Author(s) -

Mao Xuerong,

Ma Xiao,

Zhang Shuwei,

Hu Hongwen,

Zhu Chengjian,

Cheng Yixiang

Publication year - 2013

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201300545

Subject(s) - regioselectivity , chemistry , nitrobenzene , catalysis , polar effect , substrate (aquarium) , medicinal chemistry , organic chemistry , oceanography , geology

A highly efficient, Ag I /K 2 S 2 O 8 ‐mediated regioselective phosphonation reaction has been developed by using electron‐deficient directing groups. These phosphonation reactions were performed with N , N ‐dialkylbenzamides, N , N ‐dialkylbenzenesulfonamides, and nitrobenzene. This method has a broad substrate scope and offers facile construction of C–P bonds.

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