Tröger's Base Derived Phosphanes for Suzuki–Miyaura and Buchwald–Hartwig Cross‐Coupling Reactions | Zendy

Pereira Raul | Zendy; Cvengroš Ján | Zendy

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Tröger's Base Derived Phosphanes for Suzuki–Miyaura and Buchwald–Hartwig Cross‐Coupling Reactions

Author(s) -

Pereira Raul,

Cvengroš Ján

Publication year - 2013

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201300519

Subject(s) - chemistry , aniline , aryl , base (topology) , palladium , combinatorial chemistry , coupling reaction , catalysis , amination , medicinal chemistry , organic chemistry , polymer chemistry , mathematical analysis , alkyl , mathematics

A library of bis(phosphane) ligands based on the 2,8‐substituted Tröger's base scaffold was synthesized through an efficient two‐step protocol by starting from a commercially available aniline. The new ligands proved their efficiency in palladium‐catalyzed Suzuki–Miyaura cross‐coupling reactions and Buchwald–Hartwig aminations of aryl chlorides and bromides.

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