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Metal‐Free Oxidative Carbon‐Heteroatom Bond Formation Through C–H Bond Functionalization
Author(s) -
Samanta Rajarshi,
Matcha Kiran,
Antonchick Andrey P.
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201300286
Subject(s) - chemistry , surface modification , heteroatom , oxidative coupling of methane , combinatorial chemistry , coupling reaction , organic chemistry , ring (chemistry) , catalysis
Direct methods of carbon‐heteroatom bond formation through functionalization of non‐reactive C–H bonds represent an attractive approach to the synthesis of interesting products. This review focuses on the development of metal‐free coupling methods for unactivated compounds under oxidative reaction conditions. The utility of these methods in syntheses of desired products and the mechanisms of their formation are discussed with numerous examples.