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Organic and Organometallic Derivatives of Propargylallene: Syntheses, Structures, Reactivity and Rearrangements
Author(s) -
McGlinchey Michael J.,
Hopf Henning
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201300250
Subject(s) - chemistry , reactivity (psychology) , reagent , organometallic chemistry , transition metal , platinum , group 2 organometallic chemistry , metal , organic chemistry , combinatorial chemistry , stereochemistry , computational chemistry , polymer chemistry , molecule , catalysis , medicine , alternative medicine , pathology
Propargylallenes offer the varied reactivity patterns of two different multiple bond linkages either separately or in concert. Their syntheses, structures, rearrangement mechanisms and synthetic utility are reviewed, together with their behaviour when treated with transition‐metal reagents such as gold(I), silver(I), platinum metals or metal carbonyls.