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Diametrically Opposed Carbenes on an α‐Cyclodextrin: Synthesis, Characterization of Organometallic Complexes and Suzuki–Miyaura Coupling in Ethanol and in Water
Author(s) -
Guitet Maxime,
Marcelo Filipa,
de Beaumais Ségolène Adam,
Zhang Yongmin,
JiménezBarbero Jesús,
Tilloy Sébastien,
Monflier Eric,
Ménand Mickaël,
Sollogoub Matthieu
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201300190
Subject(s) - carbene , chemistry , palladium , catalysis , cyclodextrin , ethanol , organic chemistry , combinatorial chemistry , coupling (piping) , coupling reaction , organometallic chemistry , polymer chemistry , materials science , metallurgy
Two carbene‐based ligands have been attached to perbenzylated and permethylated cyclodextrins. Their palladium complexes were synthesized, characterized and used as catalysts in Suzuki–Miyaura coupling reactions both in ethanol and water.