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Palladium‐Catalyzed Formation of C=C Bonds: A Regioselective Strategy for the Synthesis of 2‐Vinylfurans by 1,2‐H Shift of Palladium–Carbene Complexes
Author(s) -
Zhan Haiying,
Lin Xiulian,
Qiu Yanying,
Du Zuodong,
Li Peixian,
Li Yongjian,
Cao Hua
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201300016
Subject(s) - palladium , chemistry , regioselectivity , catalysis , carbene , sequence (biology) , combinatorial chemistry , organic chemistry , medicinal chemistry , biochemistry
A convenient method to synthesize vinylfurans through a palladium‐catalyzed cyclization/1,2‐H shift sequence under mild conditions is described. This is an efficient strategy to synthesize 2‐vinylfurans from ene–yne ketones, and the corresponding products are obtained in good yields.