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General and Efficient α‐Oxygenation of Carbonyl Compounds by TEMPO Induced by Single‐Electron‐Transfer Oxidation of Their Enolates (Eur. J. Org. Chem. 24/2012)
Author(s) -
Dinca Emanuela,
Hartmann Philip,
Smrček Jakub,
Dix Ina,
Jones Peter G.,
Jahn Ullrich
Publication year - 2012
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201290063
Subject(s) - chemistry , chemoselectivity , hexafluorophosphate , oxygenation , electron transfer , organic chemistry , cover (algebra) , photochemistry , combinatorial chemistry , catalysis , ionic liquid , ecology , biology , mechanical engineering , engineering
The cover picture shows that treatment of a wide variety of carbonyl compounds with base, TEMPO, and ferrocenium hexafluorophosphate leads to the formation of a‐oxygenated carbonyl compounds in mostly good yields and excellent chemoselectivity. A comprehensive picture of these oxygenation reactions is presented by U. Jahn et al. on p. 4461ff. This occurs before the background of the beautiful Prague castle and town, which will host the 4th EuCheMS Chemistry Congress, August 26–30, 2012.