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Synthesis of Fluorinated exo ‐Glycals through Modified Julia Olefination
Author(s) -
Habib Samuel,
Larnaud Florent,
Pfund Emmanuel,
Lequeux Thierry,
Fenet Bernard,
Goekjian Peter G.,
Gueyrard David
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201201719
Subject(s) - chemistry , enol , fluorine , organic chemistry , catalysis
An efficient synthesis of fluorinated enol ethers derived from carbohydrates is reported. A modified Julia olefination reaction of functionalized lactones with fluorine‐substituted sulfones gives the corresponding monofluorinated tri‐ or tetrasubstituted exo ‐glycals.