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Synthesis of Chiral Allylic Thioesters: Enantio‐ and Regioselective Iridium‐Catalyzed Allylations of KSAc
Author(s) -
Gao Ning,
Zhao Xiaoming
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201201640
Subject(s) - chemistry , allylic rearrangement , regioselectivity , iridium , enantioselective synthesis , catalysis , combinatorial chemistry , organic chemistry , medicinal chemistry
Chiral allylic thioesters were synthesized through a direct iridium‐catalyzed asymmetric allylation of KSAc in the presence of KOAc. This strategy provided branched allylic thioesters in good yields with the high levels of enantioselectivity.