Premium
Synthesis, Electrochemistry, and Hierarchical Self‐Organization of Fulleropyrrolidine–Phthalimide Dyads
Author(s) -
Mitrović Aleksandra,
Todorović Nina,
Žekić Andrijana,
Stanković Dalibor,
Milić Dragana,
Maslak Veselin
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201201631
Subject(s) - phthalimide , chemistry , electrochemistry , supramolecular chemistry , acceptor , microwave irradiation , self assembly , redox , photochemistry , combinatorial chemistry , crystallography , electrode , organic chemistry , catalysis , crystal structure , condensed matter physics , physics
A series of novel fulleropyrrolidine–phthalimide dyads was synthesized and their electrochemical and self‐assembly properties were investigated. Efficient synthesis of acceptor–acceptor dyads was performed under microwave irradiation. Fine‐tuning of the second redox potentials in the dyads was achieved by varying the length of the aliphatic spacer (C 2 to C 12 ) between the fulleropyrrolidine and phthalimide moieties. Shape‐shifting and supramolecular polymorphism were observed for these compounds during self‐assembly.