Regio‐ and Stereoselective Olefination of Phenol Carbamates through C–H Bond Functionalization | Zendy

Li Bin | Zendy; Ma Jianfeng | Zendy; Liang Yujie | Zendy; Wang Nuancheng | Zendy; Xu Shansheng | Zendy; Song Haibin | Zendy; Wang Baiquan | Zendy

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Regio‐ and Stereoselective Olefination of Phenol Carbamates through C–H Bond Functionalization

Author(s) -

Li Bin,

Ma Jianfeng,

Liang Yujie,

Wang Nuancheng,

Xu Shansheng,

Song Haibin,

Wang Baiquan

Publication year - 2013

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201201574

Subject(s) - chemistry , carbamate , stereoselectivity , alkyne , phenol , ruthenium , rhodium , catalysis , surface modification , organic chemistry , combinatorial chemistry , medicinal chemistry

Two pathways that can be used to access ortho ‐olefinated phenol carbamate, including a ruthenium(II)‐catalyzed oxidative olefination of phenol carbamate with acrylates and a rhodium(III)‐catalyzed alkyne hydroarylation of phenol carbamate with internal alkynes through direct C–H activation, are reported. Both reactions afford substituted alkenes in a highly regio‐ and stereoselective manner.

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