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Cascade Palladium‐ and Copper‐Catalysed Aromatic Heterocycle Synthesis: The Emergence of General Precursors
Author(s) -
Ball Catherine J.,
Willis Michael C.
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201201386
Subject(s) - chemistry , palladium , cascade , copper , sulfur , carbon fibers , coupling reaction , organic chemistry , nitrogen , combinatorial chemistry , catalysis , polymer chemistry , materials science , chromatography , composite number , composite material
Abstract Several privileged starting materials that allow access to a variety of different heterocyclic scaffolds through judicious choice of reaction conditions (and coupling partner) have emerged. This microreview focuses on the development and use of four of these starting material types in cascade reactions involving the palladium‐ or copper‐catalysed formation of aromatic carbon–nitrogen, carbon–oxygen or carbon–sulfur bonds.