Intramolecular Cascade Hydroarylation/Cycloisomerization Strategy for the Synthesis of Polycyclic Aromatic and Heteroaromatic Systems | Zendy

Storch Jan | Zendy; Bernard Martin | Zendy; Sýkora Jan | Zendy; Karban Jindřich | Zendy; Čermák Jan | Zendy

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Intramolecular Cascade Hydroarylation/Cycloisomerization Strategy for the Synthesis of Polycyclic Aromatic and Heteroaromatic Systems

Author(s) -

Storch Jan,

Bernard Martin,

Sýkora Jan,

Karban Jindřich,

Čermák Jan

Publication year - 2013

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201201329

Subject(s) - cycloisomerization , helicene , chemistry , intramolecular force , phenanthrenes , phenanthrene , cascade , stereochemistry , molecule , combinatorial chemistry , catalysis , organic chemistry , chromatography

A new PtCl 2 /PtCl 4 ‐catalyzed hydroarylation/cycloisomerization cascade reaction leading to the formation of two aromatic or heteroaromatic rings in one step is reported. The strategy developed is exemplified by the synthesis of the 5,6‐dihydrobenzo[ c ]phenanthrene and 6 H ‐naphtho[2,1‐ c ]chromene skeletons. Attempts to prepare [8]helicene‐like molecules are also discussed.

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