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Metal‐Free Synthesis of Secondary Arylamines: An Aliphatic‐to‐Aromatic Transformation
Author(s) -
Barros M. Teresa,
Dey Suvendu S.,
Maycock Christopher D.
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201201263
Subject(s) - chemistry , primary (astronomy) , transformation (genetics) , organic chemistry , metal , combinatorial chemistry , biochemistry , gene , physics , astronomy
An efficient method for the N ‐arylation of primary and some secondary amines using 2‐halocyclohex‐2‐enones in an aliphatic‐to‐aromatic transformation in the presence of a substoichiometric amount of p TsOH has been developed.