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Tsuji–Trost N ‐Allylation with Allylic Acetates by Using a Cellulose–Palladium Catalyst
Author(s) -
Vaddula Buchi Reddy,
Saha Amit,
Varma Rajender S.,
Leazer John
Publication year - 2012
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201201241
Subject(s) - chemistry , allylic rearrangement , catalysis , palladium , cellulose , organic chemistry , yield (engineering) , ligand (biochemistry) , combinatorial chemistry , biochemistry , materials science , receptor , metallurgy
Allylic amines were synthesized by a simple procedure using a biodegradable and easily recyclable heterogeneous cellulose–Pd catalyst through N ‐allylation of primary and secondary amines. The scope of this protocol includes aliphatic and benzylamines with substituted and unsubstituted allyl acetates and culminates in high yield syntheses. The highlights of the protocol include a ligand‐free reaction, simple workup, and catalyst recyclability.