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One‐Pot Synthesis of Symmetrical Diaryl Trithiocarbonates through Copper‐Catalyzed Coupling of Aryl Compounds, Sodium Sulfide, and Carbon Disulfide
Author(s) -
Gholinejad Mohammad
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201201126
Subject(s) - chemistry , aryl , carbon disulfide , halide , sodium sulfide , sulfide , catalysis , copper , coupling reaction , combinatorial chemistry , sodium , carbon fibers , organic chemistry , alkyl , materials science , composite number , composite material
In this study, a protocol for the synthesis of symmetrical diaryl trithiocarbonates through the one‐pot copper‐catalyzed coupling reaction of sodium sulfide, carbon disulfide, and aryl compounds in DMF solution is presented. This method allows the synthesis of symmetrical diaryl trithiocarbonates without the use of highly toxic thiophosgene, and also, commercially available aryl halides were used instead of less available, toxic thiols.