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Self‐Metathesis of Polyol Allyl Ethers towards Carbohydrate‐Based Oligohydroxy Derivatives
Author(s) -
Tober Maike,
Thiem Joachim
Publication year - 2013
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201201083
Subject(s) - pentaerythritol , chemistry , polyol , alkyd , metathesis , organic chemistry , sorbitol , carbohydrate chemistry , aldose , polymer chemistry , polymerization , glycoside , polyurethane , polymer , fire retardant , coating
Various allyl ethers of 1,4‐anhydro‐ D ‐sorbitol and pentaerythritol were synthesised as starting materials for self‐metathesis reactions. Thus, dimeric compounds having six free hydroxy groups became accessible and should be used as potential analogues of dipentaerythritol for alkyd resin formation.