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A Highly Nucleophilic Multifunctional Chiral Phosphane‐Catalyzed Asymmetric Intramolecular Rauhut–Currier Reaction
Author(s) -
Zhang XiaoNan,
Shi Min
Publication year - 2012
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201200940
Subject(s) - chemistry , intramolecular force , nucleophile , cyclopentene , catalysis , cyclohexene , enantioselective synthesis , stereochemistry , combinatorial chemistry , medicinal chemistry , organic chemistry
An asymmetric variant of the intramolecular Rauhut–Currier (RC) reaction can be achieved using a highly nucleophilic multifunctional chiral phosphane; the corresponding cyclopentene and cyclohexene derivatives are produced in moderate to good yields and with good to excellent enantioselectivities.