Trideuteriomethoxylation of Aryl and Heteroaryl Halides | Zendy

Dash Pragyanditi | Zendy; Janni Manojkumar | Zendy; Peruncheralathan S. | Zendy

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Trideuteriomethoxylation of Aryl and Heteroaryl Halides

Author(s) -

Dash Pragyanditi,

Janni Manojkumar,

Peruncheralathan S.

Publication year - 2012

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201200753

Subject(s) - chemistry , halide , aryl , denticity , catalysis , ligand (biochemistry) , combinatorial chemistry , medicinal chemistry , organic chemistry , crystal structure , alkyl , receptor , biochemistry

Direct access to trideuteriomethoxylated aromatic and heteroaromatic compounds has been developed. Various aryl and heteroaryl halides underwent d 3 ‐methoxylation under mild reaction conditions by using a catalyst system composed of the commercially available monodentate phosphane ligand t BuXPhos and Pd(OAc) 2 . Inexpensive CD 3 OD served as an efficient trideuteriomethoxylating agent.

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