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Palladium‐Mediated Heck‐Type Reactions of [(Bromodifluoromethyl)sulfonyl]benzene: Synthesis of α‐Alkenyl‐ and α‐Heteroaryl‐Substituted α,α‐Difluoromethyl Phenyl Sulfones
Author(s) -
Surapanich Nakin,
Kuhakarn Chutima,
Pohmakotr Manat,
Reutrakul Vichai
Publication year - 2012
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201200613
Subject(s) - chemistry , sulfonyl , palladium , benzene , styrene , benzene derivatives , medicinal chemistry , catalysis , heck reaction , organic chemistry , chemical synthesis , copolymer , polymer , biochemistry , in vitro , alkyl
Palladium‐catalyzed Heck‐type reactions of [(bromodifluoromethyl)sulfonyl]benzene ( 1 ) with styrene derivatives and heteroaromatic compounds successfully gave α‐alkenyl‐ and α‐heteroaryl‐substituted α,α‐difluoromethyl phenyl sulfones, respectively.