Synthesis of Spinosyn Analogues for Modern Crop Protection | Zendy

Tietze Lutz F. | Zendy; Schützenmeister Nina | Zendy; Grube Alexander | Zendy; Scheffer Timo | Zendy; Baag Mohammad Merajuddin | Zendy; Granitzka Markus | Zendy; Stalke Dietmar | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis of Spinosyn Analogues for Modern Crop Protection

Author(s) -

Tietze Lutz F.,

Schützenmeister Nina,

Grube Alexander,

Scheffer Timo,

Baag Mohammad Merajuddin,

Granitzka Markus,

Stalke Dietmar

Publication year - 2012

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201200600

Subject(s) - chemistry , moiety , cyclopentene , stereochemistry , rhamnose , cyclopentanone , heck reaction , organic chemistry , catalysis , palladium , polysaccharide

New spinosyn analogues 3 with an arene group as ring A and containing a L ‐rhamnose moiety have been prepared. The key step in the synthesis of 3 is a Pd‐catalyzed twofold Heck reaction of glycosylated bromoarene 4 , containing an iodovinyl side chain and a tri‐ O ‐methyl‐ L ‐rhamnose moiety with the cyclopentene‐annulated macrolactone 5 . Compounds 3 may be of interest as new insecticides.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research