Premium
Oxidative Ring Opening of 1,3‐Diarylbenzo[ c ]heterocycles Using m ‐CPBA: Preparation of 1,2‐Diaroylbenzenes
Author(s) -
Nandakumar Meganathan,
Sivasakthikumaran Ramakrishnan,
Mohanakrishnan Arasambattu K.
Publication year - 2012
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201200311
Subject(s) - chemistry , oxidative cleavage , oxidative phosphorylation , ring (chemistry) , cleavage (geology) , stereochemistry , organic chemistry , medicinal chemistry , combinatorial chemistry , catalysis , biochemistry , geotechnical engineering , fracture (geology) , engineering
An unprecedented oxidative cleavage of benzo[ c ]heterocycles using m ‐CPBA is reported. The reaction of 1,3‐diaryl benzo[ c ]heterocycles with m ‐CPBA ( meta ‐chloroperoxybenzoic acid) at room temperature for 5 min led to the formation of 1,2‐diaroylbenzenes in good to excellent yields.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom