Ruthenium‐Catalyzed Cycloisomerization and Its Application to the Synthesis of (±)‐Cinchonaminone | Zendy

Ogawa Takao | Zendy; Nakamura Tomonori | Zendy; Araki Takuya | Zendy; Yamamoto Koujirou | Zendy; Shuto Satoshi | Zendy; Arisawa Mitsuhiro | Zendy

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Ruthenium‐Catalyzed Cycloisomerization and Its Application to the Synthesis of (±)‐Cinchonaminone

Author(s) -

Ogawa Takao,

Nakamura Tomonori,

Araki Takuya,

Yamamoto Koujirou,

Shuto Satoshi,

Arisawa Mitsuhiro

Publication year - 2012

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201200260

Subject(s) - cycloisomerization , synthon , chemistry , ruthenium , catalysis , yield (engineering) , alkene , substrate (aquarium) , derivative (finance) , organic chemistry , combinatorial chemistry , diene , materials science , oceanography , natural rubber , economics , financial economics , metallurgy , geology

Ru‐catalyzed cycloisomerization of a 1,3‐diene and the alkene of an N ‐dienyl‐2‐vinylaniline substrate proceeded smoothly, leading to a 3‐exomethylene‐2‐vinylindole derivative in good yield. This useful synthon was successfully applied to the total synthesis of (±)‐cinchonaminone.

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