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Preparation of α‐Sulfonylethanone Oximes from Oxidized Hydroxylamine
Author(s) -
Liu Nan,
Yin Ping,
Chen Yue,
Deng Yong,
He Ling
Publication year - 2012
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201200133
Subject(s) - chemistry , periodate , hydroxylamine , intermolecular force , catalysis , organic chemistry , reaction conditions , metal , molecule
Abstract Alkenes react with substituted N ‐hydroxysulfonamides and tetrabutylammonium periodate under metal catalyst free conditions to give oximes in good to high yields. The reaction proceeds in a one‐pot manner, giving rise to the formation of intermolecular C–N and C–S bonds simultaneously. The method is mild, highly efficient, and convenient.