Premium
Multidentate Pyridyl‐Based Ligands in the Coordination‐Driven Self‐Assembly of Palladium Metallo‐Macrocycles (Eur. J. Org. Chem. 3/2011)
Author(s) -
Brusilowskij Boris,
Schalley Christoph A.
Publication year - 2011
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201190000
Subject(s) - chemistry , supramolecular chemistry , palladium , denticity , bipyridine , self assembly , ligand (biochemistry) , stereochemistry , combinatorial chemistry , coordination complex , metal , polymer chemistry , crystallography , crystal structure , organic chemistry , receptor , catalysis , biochemistry
The cover picture shows the formation of a dynamic combinatorial library of self‐assembled metallo‐supramolecular macrocycles. When only one equivalent of the dpppPd II precursor complex is added, the bipyridine‐based ligand selectively forms a 2:2 metallo‐supramolecular macrocycle. Complexation to the bipyridine site occurs only upon addition of a second equivalent of the metal complex. Details are discussed in the article by B. Brusilowskij and C. A. Schalley on p. 469 ff.