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Synthesis of 1,2‐Naphthalenediol Diacetates by Rhodium(II)‐Catalyzed Reaction of 1,2‐Diazonaphthoquinones with Acetic Anhydride
Author(s) -
Kitamura Mitsuru,
Kisanuki Masato,
Okauchi Tatsuo
Publication year - 2012
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201101698
Subject(s) - chemistry , acetic anhydride , catalysis , rhodium , organic chemistry , acetic acid , acid anhydride , reaction conditions , pummerer rearrangement , polymer chemistry , medicinal chemistry , epoxy
A metal‐catalyzed reaction of α‐diazocarbonyl compounds with an acid anhydride is reported. In particular, 1,2‐naphthalenediol diacetates were synthesized by the reaction of 1,2‐diazonaphthoquinones with acetic anhydride catalyzed by Rh 2 (OAc) 4 .
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