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Efficient Preparation of Anhydrous Metallic Triflates and Triflimides under Ultrasonic Activation
Author(s) -
Legrave Nathalie,
Couhert Audrey,
Olivero Sandra,
Desmurs JeanRoger,
Duñach Elisabet
Publication year - 2012
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201101686
Subject(s) - anhydrous , triflic acid , chemistry , metal , catalysis , ultrasonic sensor , inorganic chemistry , solid acid , organic chemistry , physics , acoustics
Several metallic triflates and triflimides, among them anhydrous salts, were prepared in high yields under ultrasonic activation from the corresponding metal powders andstoichiometric amounts of triflic or triflimidic acid in different solvents. Different In III and Bi III salts were tested as catalysts in hydrothiolation of olefins and in hydroarylation processes, respectively.