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Molecular and Macromolecular Engineering with Viologens as Building Blocks: Rational Design of Phosphorus–Viologen Dendritic Structures
Author(s) -
Katir Nadia,
Majoral Jean Pierre,
El Kadib Abdelkrim,
Caminade AnneMarie,
Bousmina Mostapha
Publication year - 2012
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201101376
Subject(s) - viologen , dendrimer , chemistry , phosphonate , trimer , dimer , rational design , monomer , combinatorial chemistry , phosphorus , aldehyde , organic chemistry , nanotechnology , polymer , materials science , catalysis
The design of symmetric or asymmetric diversely functionalized monomer, dimer, or trimer viologens and the design of phosphorus building blocks allows the synthesis of unique types of mix phosphorus–viologen dendrimers. Strategies for the preparation of dendrimers of generations 0 and 1 are presented as are those for various dendrons. These methods exhibit broad applicability, high efficiency and usability, and are compatible with the presence of various functional groups (aldehyde, cyano, phenol, phosphonate, brominated groups).