The Development of Domino Reactions Incorporating the Heck Reaction: The Formation of N‐Heterocycles | Zendy

Rixson James E. | Zendy; Chaloner Thomas | Zendy; Heath Charles H. | Zendy; Tietze Lutz F. | Zendy; Stewart Scott G. | Zendy

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The Development of Domino Reactions Incorporating the Heck Reaction: The Formation of N‐Heterocycles

Author(s) -

Rixson James E.,

Chaloner Thomas,

Heath Charles H.,

Tietze Lutz F.,

Stewart Scott G.

Publication year - 2012

Publication title -

european journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.825

H-Index - 155

eISSN - 1099-0690

pISSN - 1434-193X

DOI - 10.1002/ejoc.201101305

Subject(s) - domino , heck reaction , chemistry , cascade reaction , palladium , substrate (aquarium) , catalysis , combinatorial chemistry , ring (chemistry) , organic chemistry , oceanography , geology

The methodological development of a series of domino or cascade reactions affording a series of N‐heterocycles is described. The rapid formation of these ring systems is in each case associated with the incorporation of a Heck reaction at either an early or a late stage of the domino process. A range of catalytic conditions and substrate modifications for optimisation of domino Tsuji–Trost/Heck, Buchwald–Hartwig/Heck and Heck/carbopalladation reaction sequences are reported.

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