Premium
A New Solvent‐Free Reaction for the Preparation of Alkoxysilane from Cyclic Ethers, Alcohols, or Carbonyl Compounds
Author(s) -
Pehlivan Leyla,
Métay Estelle,
Boyron Olivier,
Demonchaux Patrice,
Mignani Gérard,
Lemaire Marc
Publication year - 2011
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201100489
Subject(s) - chemistry , organic chemistry , primary (astronomy) , solvent , alcohol , ring (chemistry) , aldehyde , polymer chemistry , catalysis , physics , astronomy
The 1,1,3,3‐tetramethyldisiloxane/Pd/C system is reported here as a new method to accomplish the ring‐opening of ethers and epoxides to give protected alcohols. The approach can also be used for the protection of primary or secondary alcohols and for the reduction of aldehydes and ketones to obtain alkoxysilanes.