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Synthesis of a Range of Iodine(III) Compounds Directly from Iodoarenes
Author(s) -
Merritt Eleanor A.,
Olofsson Berit
Publication year - 2011
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/ejoc.201100360
Subject(s) - iodobenzene , chemistry , alkyne , iodine , salt (chemistry) , solvent , halogenation , organic chemistry , combinatorial chemistry , catalysis
The first direct synthesis of an alkynyl(phenyl)iodonium salt from iodobenzene and an unprotected alkyne is described. The synthesis of the corresponding alkenyl(phenyl)iodonium salt is achieved from the TMS‐alkyne, simply by means of changing the solvent. The one‐pot synthesis of 1‐arylbenziodoxolones and other iodine(III) compounds from iodine(I) precursors is also presented.